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The ray switch shader has been split up into two ray_switch_shader and ray_switch_rgba nodes, for switching between shaders and one for switching between texture colors respectively. Adopted from the common shaders, there is also a vanilla color mixing shader mix_rgba. This makes it possible to mix shaders efficiently, using the new mix_shader node to blend or add two shaders including all their light AOVs.

Shader mixing: surface, hair and volume shaders now output closures rather than colors.

This supersedes the density volume shader, which has been removed. Displacement can be used to add more detail to volumes.

Fire can be rendered using blackbody emission driven by temperature. The shader provides independent control of density, scattering color and transparency, in a way that is energy conserving by default.

Standard Volume: a new standard_volume shader was added, usable for rendering a wide variety of volumes.

The older hair shader is still available but considered deprecated.

Standard Hair: a new physically based standard_hair shader was added, with much more accurate specular and transmissive scattering, better diffuse scattering for dirty hair, melanin randomization, and simple and intuitive parameters.

The standard shader is still available but considered deprecated. Standard Surface: a new standard_surface shader was added, with intuitive and energy conserving parameters, a secondary specular coat with separate normal, metallic Fresnel, thin surface support and more.

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See the Arnold 5.0.0.0, Arnold 5.0.0.1, Arnold 5.0.0.2 release notes for the full list of core enhancements and fixes.